There were few surprises on the team sheet which featured stalwart Anfield fixtures such as Mohamed Salah, Roberto Firmino, Sadio Mané, James Milner and Emre Can, reports Efe.
Left-back Andy Robertson and right-back Trent Alexander-Arnold, two youngsters who have soon made a name for themselves among Liverpool fan favorites, were also off to face Madrid.
The Reds are to train at the Olimpiyskiy Stadium on Friday before the final there the following day.
The full 24-squad was as follows:
Goalkeepers: Loris Karius, Simon Mignolet, Danny Ward
Defenders: Trent Alexander-Arnold, Nathan Clyne, Virgil van Dijk, Dejan Lovren, Ragnar Klavan, Alberto Moreno, Andrew Robertson, Nathaniel Phillips
Midfield: Georginio Wijnaldum, James Milner, Jordan Henderson, Adam Lallana, Emre Can, Curtis Jones, Rafa Camacho
Forwards: Roberto Firmino, Mohamed Salah, Sadio Mané, Danny Ings, Dominic Solanke, Ben Woodburn